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测试与分析 黄鑫 等·类石墨烯对 NR/BR 硫化胶力学性能及动态生热性能影响
(3)硫化胶的不同温度下的动态剪切损耗模量 G''、
储能模量 G' 降低,并且动态生热降低,且在高温下,
填料对硫化胶 G' 和 G'' 的影响减小。
参考文献 :
[1] 程帅帅 . 高性能石墨烯天然橡胶复合材料的制备及性能研究
[D]. 中北大学 .
[2] Noguchi F, Zhou Y, Kosugi K, et al. Effect of strain-induced
crystallization on the tearstrength of natural rubber/styrene
butadiene rubber blend[J]. Advances in PolymerTechnology,
2018, 37(6):1 850-1 858.
[3] Chen L, Guo X, Luo Y, et al. Effect of novel supported
vulcanizing agent on theinterfacial interaction and
strain-induced crystallization properties of natural
rubbernanocomposites[J]. Polymer, 2018, 148:390-399
图 5 SG3-G/N330 并用量对硫化胶动态性能下降程度随
[4] 赵旭涛,刘大华 . 合成橡胶工业手册 [M]. 化学工业出版社,
温度的变化
2006.
Influence of graphene like materials on the mechanical properties and
dynamic heat generation performance of NR/BR vulcanizates
3
2
Huang Xin , Xie Shengwu , Zhang Yong , Deng Tao 1*
1
(1. Qingdao University of Science and Technology, Qingdao 266042, Shandong, China;
2. Southern Graphite Research Institute (Hunan) Co. LTD., Changsha 410000, Hunan, China;
3. Letone Hydraulic Technology Co. LTD., Luohe 462000, Henan, China)
Abstract: The study investigated the application of a novel graphene like material SG3-G in ordinary
conveyor belt coverlay. By replacing N330 carbon black, the processing performance, physical and
mechanical properties, and dynamic heat generation performance of the adhesive were investigated. The
results showed that the substitution of SG3-G from 0 parts to 20 parts prolonged the t 10 and t 90 of the mixed
rubber; The Mooney viscosity decreased significantly; The hardness, tensile strength, and tensile stress of
vulcanized rubber slightly decrease; The change in elongation at break and permanent deformation at break
is not significant; The tear strength has significantly decreased, while the dynamic heat generation has also
decreased.
Key words: natural rubber; polybutadiene rubber; graphene-like ; conveyor belt; dynamic heat
generation
(R-03)
年
2024 第 50 卷 ·43·