This paper employs different peroxide/sulfur carrier combinations and vulcanization systems to test the vulcanization characteristics and mechanical properties of SBR/POE blended rubber, exploring the impact of sulfur carriers on the vulcanization process and properties of the blend. The study shows that the BIPB/DTDM and BIPB/TMTD/DTDM vulcanization systems can enhance the vulcanization reaction rate of the blended rubber; the tensile strength, modulus at a given extension, hardness, and wear resistance of the BIPB/TMTD, BIPB/DTDM, and BIPB/TMTD/DTDM combination systems are all higher than those of BIPB/S, but the elongation at break is lower, and the aging properties are poorer.